彭孝军的个人简介
彭孝军,男,1962年出生,博士学位,教授,博士研究生导师。国家杰出青年基金获得者(2007),国务院学科评议组成员(2009-)。现任精细化工国家重点实验室主任,辽宁省精细化工工程技术中心主任,中国染料标准化技术委员会副主任,教育部科学技术委员会化学化工学部委员,中国化工学会精细化工委员会委员,美国染料与纺织化学协会会员,大连市石化行业协会专家委员会副主任。
2017年11月,当选2017年中国科学院院士。
人物经历
1978年就读于大连理工大学精细化工专业,1982年获学士学位,随后在武汉染料厂工作,1983年8月起为大连理工大学精细化工专业研究生,1986年获硕士学位,1989年获博士学位,1990~1992年为南开大学有机化学博士后。1992年回大连理工大学化工学院工作,先后在瑞典斯德哥尔摩大学和美国西北大学做访问学者。1995年辽宁省先进青年科技工作者,2000年“大连市十大科技青年” ,2000年被评为教育部“跨世纪优秀人才”, 2001年国务院特殊津贴获得者。
任免信息
2017年11月28日,彭孝军当选2017年中国科学院院士(化学部)。
研究领域
1、生物分子荧光探针
高稳定性、长波长、大Stockes位移的荧光染料及其在生物芯片、荧光PCR、DNA检测、蛋白质分析、荧光免疫分析、DNA测序、细胞内小分子(离子)检测中的应用。
2、功能性染料、颜料及其工业应用
染料超分子体系的光诱导电子转移、分子内电荷转移、分子内质子转移、分子功能的调控,数码喷墨用染料与颜料。
研究项目
科技部973前期研究项目“模拟光合作用将太阳能转化为化学能”、教育部重大项目“光诱导电子转移的若干重大应用研究”、国家自然科学基金项目“酶诱导生物分子荧光探针”、“光驱动氧化反应模拟光合作用研究”等。
指导硕、博士生研究方向:
⒈ (硕士生、博士生)应用化学、精细化工:
①染料及生物分子荧光探针
②超分子光化学与器件
⒉ (博士生)生物化工、分析化学:
①生物分子荧光探针:细胞内小分子荧光探针、DNA及RNA选择性荧光探针
主要论著
⒈ Xiaojun Peng,* Jianjun Du,Jiangli Fan,* Yunkou Wu,Jingyun Wang,Jianzhang Zhao and Tao Xu,Selective and Ratiometric Fluorescence Sensor for Imaging Cd2+ in Living Cells. Journal of the American Chemical Society. 2007,129 ⑹,1500 -1501
⒉ Xiaojun Peng*,Yongqian Xu,Shiguo Sun,Yunkou Wu,Jiangli Fan. A ratiometric fluorescent sensor for phosphates: Zn2+ - enhanced ICT and ligand competition. Organic & Biomolecular Chemistry. 2007,5,226u2013228
⒊ Yunkou Wu,Xiaojun Peng*,Jiangli Fan, Maozhong Tian,Jianzhang Zhao and Shiguo Sun. Fluorescence Sensing of Anions Based on Inhibition of Excited-State Intramolecular Proton Transfer. Journal of Organic Chemistry. 2007; 72⑴,62 - 70
⒋ Aijun Cui,Xiaojun Peng*,Jiangli Fan,Xiuying Chen,Yunkou Wu,Binchen Guo. Synthesis,spectral properties and photostability of novel boronu2013dipyrromethene dyes. Journal of Photochemistry and Photobiology A: Chemistry. 2007,186,85u201392
⒌ Binchen Guo,Xiaojun Peng*,Aijun Cui,Yunkou Wu,Maozhong Tian,Lizhu Zhang,Xiaoqiang Chen and Yunling Gao. Synthesis and Spectral Properties of New Boron Dipyrromethene Dyes. Dyes and Pigments. 2007,73,206-210
⒍ Lu,XB; Shi,L; Wang,YM; Zhang,R; Zhang,YJ; Peng,XJ; Zhang,ZC; Li,B. Design of highly active binary catalyst systems for CO2/epoxide copolymerization: Polymer selectivity,enantioselectivity,and stereochemistry control. J. Am. Chem. Soc. 2006,128⑸,1664-1674
⒎ Ai-Jun Cui,Xiao-Jun Peng,* Yun-Ling Gao and Jiang-Li Fan. 4,4-Difluoro-8-(4-nitrophenyl)-4-bora-3a,4a-diaza-s-indacene. Acta Crystallographica Section E,2006,62⑽,o4697-o4698.
⒏ Jun Hou,Xiaojun Peng,* Jifeng Liu,Yunling Gao,Xing Zhao,Shang Gao,Keli Han. A Binuclear Isocyanide Iron Azadithiolate Relevant to the Active Site of Fe-Only Hydrogenases: Synthesis,Structure and Electrochemical Properties. Eur. J. Inorg. Chem. 2006,4679u20134686
⒐ Jun Hou,Xiaojun Peng,*,Zhiyou Zhou,Shigang Sun,Xing Zhao,Shang Gao. Tris(N-pyrrolidinyl)phosphine substituted diiron dithiolate related to iron-only hydrogenase active site: Synthesis,characterization and electrochemical properties. Journal of Organometallic Chemistry,2006,691,4633-4640
⒑ Dong-Chuan Wang,Xiao-Jun Peng,* Ai-Jun Cui,Cheng He and Jiang-Li Fan. 4,4-Difluoro-3-[(4-methoxyphenyl)styryl]-1,5,7,8-tetramethyl-4-bora-3a,4a-diazas-Indacene. Acta Crystallographica Section E. 2006,E62,o5789u2013o5790
⒒ Jingyun Wang,Xiaojun Peng,Synthesis of new “biomimeticc” dye-ligands and their application in the purification of alkaline phosphatase. Separation and Purification Technology,2006,50,141u2013146
Xiuying Chen,Xiaojun Peng*,Aijun Cui,Bingshuai Wang,Li Wang,Rong Zhang. Photostabilities of novel heptamethine 3H-indolenine cyanine dyes with different N-substituents. Journal of Photochemistry and Photobiology A: Chemistry. 2006,181,79-85.
⒓ Xiaojun Peng,* Yunkou Wu,Jiangli Fan,Maozhong Tian and Keli Han. Colorimetric and Ratiometric Fluorescence Sensing of Fluoride: Tuning Selectivity in Proton Transfer. J. Org. Chem. 2005,70 (25),10524 -10531
⒔ Xiaojun Peng*,Fengling Song, Erhu Lu,Yanan Wang,Wei Zhou,Jiangli Fan and Yunling Gao,Heptamethine Cyanine Dyes with Large Stokes Shift and Strong Fluorescence:A Paradigm for Excited-State Intramolecular Charge Transfer, J. Am. Chem. Soc. 2005,127,4170-4171
⒕ Fengling Song,Xiaojun Peng,* Erhu Lu,Yanan Wang,Wei Zhou and Jiangli Fan,Tuning the photoinduced electron transfer in near-infrared heptamethinecyanine dyes,Tetrahedron Letters. 2005,46(28),4817-4820.
⒖ Hongming Wang,Yong Wang,Ke-Li Han*,and Xiao-Jun Peng*,A DFT Study of Diels-Alder Reactions of o-Quinone Methides and Various Substituted Ethenes: Selectivity and Reaction Mechanism. J. Org. Chem.. 2005,70,4910-4917
⒗ Yunkou Wu,Xiaojun Peng*,Binchen Guo,Jiangli Fan,Zhichao Zhang,Jingyun Wang. Boron Dipyrromethene Fluorophore Based Fluorescence Sensor for the Selective Imaging of Zn2+ in living Cells. Organic & Biomolecular Chemistry. 2005,3,1387 - 1392.
⒘ Gao Yunling,Peng Xiaojun*,Sun Shiguo,Chen Changneng. (Bis(2-pyridylmethyl)- (6-hydroxymethyl-2 -pyridylmethyl)-amine) (μ-oxo)-diiron(Ⅲ) tetraperchlorate. Acta Cryst.,2005,C61⑴,m13-m15.
18.Erhu Lu,Xiaojun Peng,Fengling Song and Jiangli Fan. A Novel Fluorescent Sensor for Triplex DNA. Bioorganic & Medicinal Chemistry Letters,2005,15,255-257.
19.Xiuying Chen,Jiahao Guo,Xiaojun Peng,Min Guo,Yongqian Xu,Lei Shi,Li Wang,Yunling Gao,Shiguo Sun,Shengmin Cai. Novel cyanine dyes with different methine chains as nanocrystalline solar cell sensitizers. Journal of Photochemistry and Photobiology A: Chemistry,2005,171,235u2013240.
20.Feng Shi,Hong Yang Li,Xiao Jun Peng,Rong Zhang,Xiao Qiang Chen,Jiang Li Fan,Jing Nan Cui,Li Cheng Sun,Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups,Chinese Chemical Letters,2005,16⑴,89-92
21.Liqiu Wang,Xiaojun Peng,Weibing Zhang,Fei Yin,Jingnan Cui,Xinqin Gao. Synthesis and Spectral Properties of Novel Wateru2013soluble Near-infrared Fluorescent Indocyanines. Chinese Chemical Letters,2005,16 ⑷,461-464
22.Liqiu Wang,Xiaojun Peng*,Erhu Lu,Jingnan Cui,Xinqin Gao. Novel Heptamethine 3H-Indocyanines and Their Spectral Properties. Chinese Chemical Letters,2005,16 ⑶,341-344
23.Rong Zhang,Shiguo Sun,Xiaojun Peng,Licheng Sun. Electrospray ionization mass spectrometry studies of rhenium(I) bipyridyl complexes. European Journal of Mass Spectrum,2004,10,599 - 603.
24.Gao Yun-Ling,Peng Xiao-Jun,Sun Shi-Guo,Sun Li-Cheng,Chen Chang-Neng,Liu Qiu-Tian,Huang De-Guang,Crystal Structure and Electrochemical Behavior of Copper Complex with 6-Hydroxymethyl-Substituted Tri (2-Pyridyl methyl)Amine,[CuCl(C19H20 N4O)]ClO4. Chinese Journal of Structural Chmestry,2004,11,1262-1265
25.Jiangli Fan,Yunkou Wu,and Xiaojun Peng,A Naphthalimide Fluorescent Sensor for Zn2+ Based on Photo-induced Electron Transfer. Chemistry Letters,2004,33⑽,1392-1393
26.Feng Shi,Hong Yang Li,Xiao Jun Peng,Rong Zhang,Xiao Qiang Chen,Jiang Li Fan,Li Cheng Sun,Synthesis and Photochemical Properties of a New Substituted Phenol Covalently Linked to Ruthenium (Ⅱ) Tris-bipyridine Containing Four Ester Groups as Sensitizer,Chinese Chemical Letters,2004,15⑿,1407-1410
27.Shiguo Sun,Xiaojun Peng,Mingwen Fan,Yongqian Xu,Lei Shi,Licheng Sun. Synthesis of two novel Rhenium(I) Bipyridyl photosentitive dyes. Chinese Chemical Letters,2004,15⑻,965-968
28.Shiguo Sun,Xiaojun Peng,Yongqian Xu,Lei Shi,Zhen Guo,Licheng Sun. A convenient synthesis and properties of Ru(bpy)2[bpy(CO2H)(COEt)](PF6)2 photosensitive dyes. Chinese Chemical Letters,2004,15⑻,969-972
29.Hongyang Li,Feng Shi,Yan Gao,Rong Zhang,Xiaojun Peng and Licheng Sun. Synthesis and characterisation of a high valent dinuclear Mn(Ⅲ,Ⅲ) complex of a triphenolate ligand [N4O3]3- with two extra functional groups. Journal of Chemical Research,2004,57-58
30.Fengling Song,Xiaojun Peng,Erhu Lu,Rong Zhang,Xiuying Chen,Bo Song. Syntheses,Spectral Properties and Photostabilities of Novel Water-Soluble Near-Infrared Cyanine Dyes. Journal of Photochemistry and Photobiology A: Chemistry,2004,168,53-57.
31.Fei Yin,Jianhui Liub,Xiaojun Peng. Effects of triethylene tetraamine on telomerase activity and proliferation in HeLa cells. Cell Biology International,2004,28,287-291
32.Liqiu Wang,Xiaojun Peng,Fengling Song,Erhu Lu,Jingnan Cui,Xinqin Gao,Rongwen Lu. New near-infrared indocyanines and their spectral properties in SiO2 sol-gel. Dyes and Pigments,2004,61,103-107
33.Fei Yin,Jianhui Liu and Xiaojun Peng. Triethylene tetraamine: A Novel Telomerase Inhibitor. Bioorganic & Medicinal Chemistry Letters,2003,13,3923-3926
34.Liqiu Wang,Xiaojun Peng,Rong Zhang,Jingnan Cui. Novel water-soluble fluorescent trimethine indocyanines containing N-p-carboxyl group. Chinese Chemical Letters 2003,14⑴,21-24
35.Liqiu Wang,Xiaojun Peng,Rong Zhang,Jingnan Cui,Guoquan Xu,Fenggang Wang. Syntheses and spectral properties of fluorescent trimethine sulfo-3H-indocyanine dyes. Dyes and Pigments 2002,54,107-111
36.Xiaojun Peng,Jingyun Wang,Jingnan Cui,Rong Zhang and Ying Yan. Friedel- Crafs Reaction of Bis(trichoromethyl)carbonate for the Preparation of Benzophenone. Synthetic Communications 2002,32⒂,2361-2367
33.Jingyun Wang,Xiaojun Peng and Lijia An. Kinetics of inactivation of ulva perusa kjellm alkaline by ethylenediaminetetraacetic acid disodium. J. Enzyme Inhibitor 2001,16⑷,313-319.
34.X.J.Peng,J. Sun,J.Y. Wang and D. H. Zhou,Study on The Silk Finishing Process with Epoxy Resins J. Text. Inst. 1997,88,Part 1⑵,143-148
35.Xiaojun Peng,Hai Yu,Yanhong Huang,Jingyun Wang,N,N'-Phosgenation in the Synthesis of Direct Dyes Containing The Ureylene Group,Dyes and Pigments,1996,32⑷,193-198
36.Xiaojun Peng,Jingzong Yang,A study of Oil-soluble Azo Dyes for Silver Dye-bleach Photography J. Soc. Dyers and Colourists 1995,111⑹,190-194
37.Xiaojun Peng,Jie Sun,Silk Finishing with Epoxides. J. Soc. Dyers and Colourists 1993,109⑷,159-163
38.Electrochemical Behavior of Azo Dyes in Acid/Ethanol media Dyes and Pigments 1992,20⑵, 73-81
学术成果
荧光染料功能强化的基础与应用研究,国家自然科学二等奖(2013年)
大幅面数码喷墨染料及其应用,国家技术发明二等奖(2006年)
计算机彩色喷绘墨水的研制,辽宁省科技进步一等奖(2004年)
大幅面数码喷墨染料及其应用,中国石油和化学工业技术发明一等奖(2005年)
荣誉记录
2020年5月,荣获第二届全国创新争先奖状。